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I believe the traditional use was for growing celery - cut a trench, part fill with ash, grow celery, fill trench as celery grows.
In agriculture, one study found that crops grown in soil with a compositionweight of 5% to 20% coal fly ash showed toxic levels of arsenic.
The ash from the fire is of no use what so ever other than making paths.Soot how ever is, providing it comes from natural coal not man made.Soot not ash was put round celery to stop slugs, it sticks to the slug so it cant move.It can also be put on the compost heap and as a mild tomato feed to give the tomato a deep red color